MPŠ MP&Scaron MP&Scaron MP&Scaron Avtorji

Jožef Stefan
Postgraduate School

Jamova 39
SI-1000 Ljubljana

Phone: +386 1 477 31 00
Fax: +386 1 477 31 10


Course Description

Fundamentals of Synthesis of Nanomaterials


Nanosciences and Nanotechnologies, second-level study programme


prof. dr. Barbara Malič
doc. dr. Tadej Rojac
doc. dr. Miha Čekada


Students learn the chemical and physical methods of synthesis of nanopowders, thin films, and heterostructures.


General introduction to nanomaterials – specific properties due to the nano-dimensionality, methods of characterization.
Physical methods of film deposition: introduction, materials, substrates, experimental requirements, equipment. Survey and comparison of different deposition routes.
Chemical methods of film deposition: chemical vapor deposition, chemical solution deposition, reactants, substrates, equipment. Survey and comparison of different deposition routes.
Synthesis of nanoparticles: an overview of specific features of syntheses with respect to the large specific surface of particles, particle size control, agglomeration control, particle stabilization, special methods: sol-gel, co-precipitation, polymer-assisted methods, mechano-chemical synthesis, ultrasonic activation).

Course literature:

M. Ohring, The Materials Science of Thin Films, Academic Press, San Diego, 1992.
R. Waser (Ed.), Nanoelectronics and Information Technology, Wiley-VCH, Weinheim, 2003, P. Erhart, Film Deposition Methods, 201 – 221.
G. Cao, Nanostructures and Nanomaterials, Imperial College Press, London, 2004.
B. Lee, S. Komarneni, (Eds.), Chemical Processing of Ceramics, 2nd ed., Taylor&Francis, Boca Raton, 2005,
C. N. R. Rao, A. Mueller, A. K. Cheetham, The Chemistry of Nanomaterials (Vol. 1), Wiley, Weinheim, 2004, Y. Mastai, A. Gedanken, Sonochemistry and Other Novel Methods Developed for the Synthesis of Nanoparticles, 113 - 169

Significant publications and references:

MALIČ, Barbara, KOSEC, Marija, ARČON, Iztok, KODRE, Alojz. Homogeneity issues in chemical solution deposition of Pb(Zr,Ti)O[sub]3 thin films. J. Eur. Ceram. Soc., 2005, 25, 2241-2246. [COBISS.SI-ID 1840484]
MALIČ, Barbara, ARČON, Iztok, KODRE, Alojz, KOSEC, Marija. Homogeneity of Pb(Zr, Ti)O[sub]3 thin films by chemical solution deposition : extended x-ray absorption fine structure spectroscopy study of zirconium local environment. J. appl. physi., 2006, 100, 051612-051612-8. [COBISS.SI-ID 1946212]
ROJAC, Tadej, KOSEC, Marija, ŠEGEDIN, Primož, MALIČ, Barbara, HOLC, Janez. The formation of a carbonato complex during the mechanochemical treatment of a Na[sub]2CO[sub]3-Nb[sub]2O[sub]5 mixture. Solid state ion. 2006, 177, 2987-2995. [COBISS.SI-ID 20283175]
ROJAC, Tadej, KOSEC, Marija, MALIČ, Barbara, HOLC, Janez. The application of a milling map in the mechanochemical synthesis of ceramic oxides. J. Eur. Ceram. Soc., 2006, 26, 3711-3716. [COBISS.SI-ID 20282919]
PREDOANA, Luminata, MALIČ, Barbara, KOSEC, Marija, CARATA, Mariana, CALDARARU, Monica, ZAHARESCU, Maria. Characterization of LaCoO[sub]3 powders obtained by water-based sol-gel method with citric acid. J. Eur. Ceram. Soc., 2007, 27, 4407-4411. [COBISS.SI-ID 20878631]
MALIČ, Barbara, BOERASU, Iulian, MANDELJC, Mira, KOSEC, Marija, SHERMAN, Vladimir, YAMADA, Tomoaki, SETTER, Nava, VUKADINOVIĆ, Mišo. Processing and dielectric characterization of Ba[sub](0.3)Sr(0.7)TiO[sub]3 thin films on alumina substrates. J. Eur. Ceram. Soc.. 2007, 27, 2945-2948. [COBISS.SI-ID 20664871]


Seminar and oral examination.

Students obligations:

Seminar and oral examination.