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Investigation of heterogeneous reactions of trifluoromethane with some metal oxides, hydroxides and carbonates
Heterogeneous reactions of trifluoromethane CHF3 with solid xerogel oxides, alkali hydroxides and carbonates were investigated under static and dynamic conditions and at moderate temperatures. In all cases, main reaction is fluorination characterised by a complete decomposition (mineralisation) of the fluorinating agent, CHF3, and the formation of the solid metal fluorides. …