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Surface modifications of cellulose nanomaterials: mechanisms, kinetics and their applications

Author(s): Ana Oberlintner (Author), Uroš Novak (Supervisor), Blaž Likozar (Co-Supervisor)

Year: 2023

Type: Doctoral dissertation

Synthesized in green plants, cellulose is the most abundant natural biopolymer on the planet and is thus widely available, cheap and renewable. Furthermore, its hierarchical structure allows extraction of nanosized particles in the form of cellulose nanocrystals (CNCs), obtained with hydrolysis or cellulose nanofibrils (CNFs), isolated through chemical, biological pretreatment …

Identification of indoor radio environment properties based on channel state information using machine learning approaches

Author(s): Teodora Kocevska (Author), Andrej Hrovat (Supervisor), Aleksandra Rashkovska Koceva (Co-Supervisor)

Year: 2023

Type: Doctoral dissertation

Characterization of the indoor radio environment (RE) is a prerequisite for advances in the design and optimization of next-generation indoor wireless networks and for the construction of a digital twin of the building. The need for comprehensive and accurate indoor characterization will be evident in the future hyper-connected mixed real-virtual …

Microstructural analysis and evaluation OF W and W/W2C composites for fusion application

Author(s): Andreja Šestan (Author), Miran Čeh (Supervisor), Saša Novak Krmpotič (Co-Supervisor)

Year: 2023

Type: Doctoral dissertation

Fusion technology has a great potential to safely provide an inexhaustible quantity of electricity without producing greenhouse gases and minimal hazardous waste compared to conventional energy sources, such as nuclear power plants. For materials intended for fusion plasma-facing applications, the essential properties are structural stability at elevated temperature, adequate thermal …

Use of hydrated glass for synthesis of waste-based foamed glass

Author(s): Uroš Hribar (Author), Jakob König (Supervisor)

Year: 2023

Type: Doctoral dissertation

Thermal insulation materials have a strong impact on energy efficiency of buildings which are one of the main energy consumers in the EU. Thermal insulation materials are widely used and improving their properties or improving their production can therefore have a rapid impact on the efficient use of energy in …

Nanocomposites as electrocatalysts for the use in fuel cell and electrolyzer reactions

Author(s): Léonard Jean Moriau (Author), Nejc Hodnik (Supervisor)

Year: 2023

Type: Doctoral dissertation

Electrochemical energy conversion devices such as fuel cells (FCs) and water electrolyzers (WE) have attracted attention from the scientific community for their unique ability to store electrical energy in the form of hydrogen and then generate electricity by the reverse process. Unfortunately, those devices rely on a significant amount of …

Discrete aluminium compounds – towards a soluble aluminium trifluoride

Author(s): Evelin Gruden (Author), Gašper Tavčar (Supervisor)

Year: 2022

Type: Doctoral dissertation

In the past, the search for soluble aluminium trifluoride (AlF3) led to the discovery of organoaluminium compounds (AlR3) and organoaluminium fluorides. However, suitable methods for the introduction of fluorine into AlR3 are still scarce, making the discrete AlF3 and organoaluminium fluoride compounds rare. Our investigation of the reactivity of cyclic …

Alkali-activated steel slag-based materials

Author(s): Mark Češnovar (Author), Vilma Ducman (Supervisor), Srečo Davor Škapin (Co-Supervisor)

Year: 2022

Type: Doctoral dissertation

Alkali activation is a chemical process in which aluminosilicate-rich materials that dissolve in basic media at room temperature form binding phases by polycondensation. Alkali-activated materials (AAM), also called geopolymers, are inorganic aluminosilicate-based materials produced mainly from fly ashes and metallurgical slags or clays with high Al and Si content and …

Development and application of molecularly imprinted polymers for selected antidepressants and studies of their environmental fate

Author(s): Tjaša Gornik (Author), Tina Kosjek (Supervisor), Ester Heath (Co-Supervisor)

Year: 2022

Type: Doctoral dissertation

This thesis focuses on the fate of chosen antidepressants in the environment. Studied compounds belong to the class of selective serotonin reuptake inhibitors. Reportedly they do not completely mineralize by existing water treatment processes and their residues cause unwanted toxic effects in aquatic organisms. However, to date, insufficient information has …

Lead magnesium niobate titanate thick films prepared by aerosol deposition method

Author(s): Matej Šadl (Author), Hana Uršič Nemevšek (Supervisor)

Year: 2022

Type: Doctoral dissertation

The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …

Electrochemically synthesised polyaniline for gas and aqueous detection of ammonia

Author(s): Anja Korent (Author), Kristina Žužek (Supervisor)

Year: 2022

Type: Doctoral dissertation

An everyday awareness of the presence of harmful chemicals around us has led to the development of a way to report overexposure through the reactions of these compounds with specifically prepared materials - sensory elements. In this doctoral dissertation we focused on the electrochemical synthesis (electropolymerization) of conductive polymer polyaniline …