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Low-temperature sintering of piezoelectric K0.5Na0.5NbO3 ceramics

Author(s): Janez Bernard (Author), Barbara Malič (Supervisor), Andreja Benčan Golob (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

The KNN solid solution was prepared from pre-synthesized binary compounds of, sodium and potassium niobate in a 1/1 molar ratio. The KNG sintering aid was prepared by homogenizing the pre-reacted binary mixtures of alkaline reagents and germanium oxide with the Na/Ge = 1/1 and K/Ge = 1/1 molar ratios. The …

Moderately porous zirconia ceramics for dental applications

Author(s): Sebastjan Perko (Author), Tomaž Kosmač (Supervisor), Aleš Dakskobler (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

This doctoral thesis describes the preparation of moderately porous Y-TZP ceramics with improved flexural strength. The main field of application is dentistry, where the elastic mismatch between the Y-TZP material and tooth substance influences the survival rate of fixed partial dentures (FPDs). By introducing porosity into the bulk samples a …

Processing-Dependent Broadband Dielectric Properties of KTaO3 Ceramics, Films and KTa0.6Nb0.4O3 Films

Author(s): Sebastjan Glinšek (Author), Marija Kosec (Supervisor), Zdravko Kutnjak (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

KTaO3 belongs to the group of incipient ferroelectrics, which are materials important from the fundamental, as well as from the applications, point of view. It is well known in its single-crystal form; however, the processing of technologically interesting ceramics and thin films is a challenging task and knowledge of their …

A New Synthesis Route to Pb(Mg1/3Nb2/3)O3-Based Materials by the Controlled Agglomeration of Reagent Particles

Author(s): Gregor Trefalt (Author), Marija Kosec (Supervisor), Bosiljka Tadić (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

In this thesis we demonstrate a new, simple, and ecient method for the solid-state synthesis of oxides with a complex chemical composition. We modify the traditional solidstate synthesis method, which is used in the majority of ceramics laboratories around the world, in order to prepare multi-metallic oxide powders from classic …

Synthesis and Characterization of Aluminium Foams

Author(s): Irena Paulin (Author), Monika Jenko (Supervisor)

Year: 2011

Type: Doctoral dissertation

Aluminium foams are prospective class of cell materials that offer a variety of applications in fields such as lightweight structures or crash-energy management. Due to interesting combination of physical and mechanical properties, such as high stiffness at low density, high impact energy absorption, flame and heat resistance, sound absorption, aluminium …

Mercury in the Process of Cement Clinker Production and Emission Control

Author(s): Tanja Ljubič Mlakar (Author), Milena Horvat (Supervisor)

Year: 2011

Type: Doctoral dissertation

Mercury is a very toxic element. Due to its volubility it is present everywhere in the environment at ambient temperature. High temperature processes increased levels of mercury on the global scale. Global and European action plans were established to reduce mercury emissions and remove mercury from the environment. Cement plants …

Innovative electroconductive ceramic composites based on Si3N4

Author(s): Aljoša Maglica (Author), Tomaž Kosmač (Supervisor), Kristoffer Krnel (Co-Supervisor)

Year: 2011

Type: Doctoral dissertation

This thesis describes an investigation of electrically conductive composites based on Si3N4 with dispersed TiN or ZrN particles fabricated by an in-situ composite method. The influence of the amount of conductive phase of the Si3N4/TiN and Si3N4/ZrN composites on the density, the flexural strength and the electrical conductivity were evaluated. …

Migration of critical radionuclides in the area of former uranium mine Žirovski vrh

Author(s): Marko Štrok (Author), Borut Smodiš (Supervisor)

Year: 2011

Type: Doctoral dissertation

A study of the migration of critical radionuclide in the area of the former uranium mine of Žirovski vrh in Slovenia was performed. Critical natural radionuclides are defined as the long-lived natural radionuclides from the uranium-radium decay chain, which are 238U, 234U, 230Th, 226Ra, 210Pb and 210Po. In the area …

NMR Study of Photoisomerization in Bulk and Confined Liquid Crystals

Author(s): Blaž Zupančič (Author), Boštjan Zalar (Supervisor)

Year: 2010

Type: Doctoral dissertation

Deuteron nuclear magnetic resonance was used to study the phase separation behavior of photoisomerizable liquid crystal diheptylazobenzene (7AB). Under UV illumination, the elongated trans molecules are converted to boomerang shaped cis form, creating a binary trans-7AB and cis-7AB mixture. It was demonstrated that the concentration of both components can be …

Structural and electrical properties of 0.65PMN-0.35PT thick films on different substrates

Author(s): Hana Uršič Nemevšek (Author), Marija Kosec (Supervisor), Marko Hrovat (Co-Supervisor)

Year: 2010

Type: Doctoral dissertation

A starting powder with the nominal composition 0.65Pb(Mg1/3Nb2/3)O3–0.35PbTiO3 (0.65PMN–0.35PT), which corresponds to the morphotropic phase boundary (MPB) composition, was prepared by mechanochemical activation followed by attritor milling and low-temperature calcination at 700°C. It had a narrow particle size distribution with the median particle size equal to 0.3 μm. From the …