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Cold sintering of lead-free ferroelectric perovskites

Author(s): Samir Salmanov (Author), Mojca Otoničar (Supervisor), Danjela Kuščer Hrovatin (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Fabrication of electroceramics usually requires high sintering temperatures of 800 to 1400 °C, which can unintentionally lead to problems such as volatilization of species, formation of secondary phases and excessive grain growth. These problems can cause inhomogeneous microstructures, non-stoichiometric chemical compositions and limited material functionality. Therefore, there is a need …

Charge compensation mechanisms and twinning in doped SnO2-based ceramics

Author(s): Sara Tominc (Author), Aleksander Rečnik (Supervisor), Nina Daneu (Co-Supervisor)

Year: 2021

Type: Doctoral dissertation

Tin (IV) oxide, SnO2 (cassiterite), is an n-type semiconductor with an advantageous combination of chemical, electric and optical properties that make it suitable for a range of applications, from solid-state gas sensors, transparent conductive coatings, oxidation catalysts and varistors. In varistor ceramics, grain growth studies are of particular interest, because …

Sintering and phase transition behaviour of sodium niobate

Author(s): Jurij Koruza (Author), Barbara Malič (Supervisor), Tadej Rojac (Co-Supervisor)

Year: 2013

Type: Doctoral dissertation

Sodium niobate (NaNbO3) is the end member of several alkaline niobate-based solid solutions, which represent an important group of environment-friendly lead-free piezoceramics. Even though alkaline niobates are of considerable technological importance, problems in obtaining high densities and a fine-grained microstructure are still reported and not much is known about the …

Low-temperature sintering of piezoelectric K0.5Na0.5NbO3 ceramics

Author(s): Janez Bernard (Author), Barbara Malič (Supervisor), Andreja Benčan Golob (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

The KNN solid solution was prepared from pre-synthesized binary compounds of, sodium and potassium niobate in a 1/1 molar ratio. The KNG sintering aid was prepared by homogenizing the pre-reacted binary mixtures of alkaline reagents and germanium oxide with the Na/Ge = 1/1 and K/Ge = 1/1 molar ratios. The …

Magnetically oriented films of barium ferrite

Author(s): Simona Ovtar (Author), Darja Lisjak (Supervisor)

Year: 2012

Type: Doctoral dissertation

This work had three aims. In the first part the influences of the sizes of the particles of barium ferrite (BaM) and their magnetic properties on the stability of the suspension were investigated. In second part the deposits were prepared by electrophoretic deposition (EFN) and the influence of particle size, …