Search Results (73)
Optimization of ToF-SIMS depth profiling in low-pressure H2, C2H2, CO and O2 atmosphere
Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a versatile analytical method widely used in the field of surface science and thin films. Although it gives elemental, molecular, and isotopic information, it has a very low detection limit and high lateral resolution, is fast and works with all the vacuum-compatible samples, …
Hidrothermal topochemical conversion of Bi4Ti3O12 nanoplatelets for formation of functional heterostructural perovskite titanates
In the view of designing new nanostructured materials and tailoring their functional properties, understanding the nucleation and crystal growth mechanisms is becoming increasingly important. Nowadays, one of the most addressed scientific and social problems are those facing energy shortage and global warming. People started to realize the value and importance …
Hybrid sol-gel coatings based on different acrylate derivatives for protection of aluminium alloy and steel against corrosion and biofouling
The subject of the doctoral dissertation is the development of coatings with improved protection of metals against corrosion and antifouling protection on structural steel S355 and aluminum alloy AA7075. S355 is a widely used metal in the construction, while AA7075 is mostly used in the transportation industry. Although they exhibit …
Topology-induced phenomena and caloric effects in condensed matter
The first part of the thesis deals with the impact of surface-functionalized nanoparticles (NP) can have on the stability of liquid crystal (LC) phases. Experimental data of NP concentration-driven phase transition between the isotropic and nematic phase in 5OO8 LCs were used to create a minimal mathematical model that would …
Atomically resolved transmission electron microscopy and in-situ voltage driven dynamic response of domain walls in lead-free ferroelectrics
Ferroelectric domain walls (DWs) are nano-to-atomic-scale interfaces that separate domains of different polar order. What makes DWs so interesting is their dynamic nature in an electric field, which offers an exciting potential for nanoscale and atomic-scale applications, but, also, more generally, the dynamics of DWs is linked to a fundamental …
Surface modifications of cellulose nanomaterials: mechanisms, kinetics and their applications
Synthesized in green plants, cellulose is the most abundant natural biopolymer on the planet and is thus widely available, cheap and renewable. Furthermore, its hierarchical structure allows extraction of nanosized particles in the form of cellulose nanocrystals (CNCs), obtained with hydrolysis or cellulose nanofibrils (CNFs), isolated through chemical, biological pretreatment …
The effect of surface roughness on erosion yields and distribution of impurities on fusion relevant materials
Plasma facing components (PFC) in fusion devices are exposed to plasma. Plasma-wall interaction processes are important as they impose a series of constraints on the components. The lifetime of the PFCs is dominantly determined by two processes: erosion and fuel retention. At the first wall the erosion is caused by …
Use of hydrated glass for synthesis of waste-based foamed glass
Thermal insulation materials have a strong impact on energy efficiency of buildings which are one of the main energy consumers in the EU. Thermal insulation materials are widely used and improving their properties or improving their production can therefore have a rapid impact on the efficient use of energy in …
Optimization and application of MeV time-of-flight secondary ion mass spectrometry in the standard and low primary ion beam energy mode
Time-of-flight secondary ion mass spectrometry using MeV ions (MeV ToF SIMS) has been around for a few decades as a reliable, surface-sensitive method for the detection of molecular ions having masses up to 1000 Da. It provides excellent lateral resolution of a few μm for imaging of organic samples, making …
Alkali-activated steel slag-based materials
Alkali activation is a chemical process in which aluminosilicate-rich materials that dissolve in basic media at room temperature form binding phases by polycondensation. Alkali-activated materials (AAM), also called geopolymers, are inorganic aluminosilicate-based materials produced mainly from fly ashes and metallurgical slags or clays with high Al and Si content and …