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Local mechanical properties of perovskite oxide ferroelectric materials

Author(s): Katarina Žiberna (Author), Andreja Benčan Golob (Supervisor), Hana Uršič Nemevšek (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Ferroelectric materials have the ability to convert electrical energy into mechanical energy and vice versa, which makes them widely used as sensors, actuators, and ultrasonic transducers. While their electrical and electromechanical properties are well studied, mechanical properties like Young’s modulus (E) and hardness (H) remain known to a lesser extent. …

Microstructure design and multifunctionality of barium zirconate titanate-barium calcium titanate thin films prepared by chemical solution deposition

Author(s): Sabi William Konsago (Author), Barbara Malič (Supervisor), Hana Uršič Nemevšek (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Barium zirconate titanate-barium calcium titanate 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) ceramic exhibits a high piezoelectric response in the vicinity of room temperature. It is an environment-friendly alternative to Pb(Zr1-xTix)O3 (PZT), the most used ceramic material in piezoelectric applications. Thin films meet the requirements related to the miniaturization of electronic components such as in …

Lead magnesium niobate titanate thick films prepared by aerosol deposition method

Author(s): Matej Šadl (Author), Hana Uršič Nemevšek (Supervisor)

Year: 2022

Type: Doctoral dissertation

The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …

Structural and electrical properties of 0.65PMN-0.35PT thick films on different substrates

Author(s): Hana Uršič Nemevšek (Author), Marija Kosec (Supervisor), Marko Hrovat (Co-Supervisor)

Year: 2010

Type: Doctoral dissertation

A starting powder with the nominal composition 0.65Pb(Mg1/3Nb2/3)O3–0.35PbTiO3 (0.65PMN–0.35PT), which corresponds to the morphotropic phase boundary (MPB) composition, was prepared by mechanochemical activation followed by attritor milling and low-temperature calcination at 700°C. It had a narrow particle size distribution with the median particle size equal to 0.3 μm. From the …