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Microstructure design and multifunctionality of barium zirconate titanate-barium calcium titanate thin films prepared by chemical solution deposition

Author(s): Sabi William Konsago (Author), Barbara Malič (Supervisor), Hana Uršič Nemevšek (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Barium zirconate titanate-barium calcium titanate 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) ceramic exhibits a high piezoelectric response in the vicinity of room temperature. It is an environment-friendly alternative to Pb(Zr1-xTix)O3 (PZT), the most used ceramic material in piezoelectric applications. Thin films meet the requirements related to the miniaturization of electronic components such as in …

Piezoelectric polymer films made of polyl-lactic acid for biomedical use

Author(s): Lea Gazvoda (Author), Marija Vukomanović (Supervisor)

Year: 2024

Type: Doctoral dissertation

In the field of biomedical materials, conventional approaches to tissue engineering and wound healing face limitations that encourage the exploration of innovative treatments. This work presents multifaceted exploration of piezoelectric polylactic acid (PLA) films intended for biomedical applications, from the optimization of the conditions for efficient film preparation to the …

Optimization of ToF-SIMS depth profiling in low-pressure H2, C2H2, CO and O2 atmosphere

Author(s): Jernej Ekar (Author), Janez Kovač (Supervisor)

Year: 2024

Type: Doctoral dissertation

Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a versatile analytical method widely used in the field of surface science and thin films. Although it gives elemental, molecular, and isotopic information, it has a very low detection limit and high lateral resolution, is fast and works with all the vacuum-compatible samples, …

Spatial and energy distributions of sputtered atoms in thin film deposition techniques

Author(s): Nastja Mahne (Author), Miha Čekada (Supervisor), Matjaž Panjan (Co-Supervisor)

Year: 2024

Type: Doctoral dissertation

The sputtering yield, the spatial distribution of the sputtered atoms, the energy distribution and the average energy of the sputtered atoms are important for numerous deposition techniques, as they determine the microstructure and the physical properties of the thin films. Using SRIM (Stopping and Range of Ions in Matter) simulations, …

Protection of biomedical alloys by thin films of alumina and hafnia prepared by atomic layer deposition

Author(s): Ivan Spajić (Author), Ingrid Milošev (Supervisor)

Year: 2022

Type: Doctoral dissertation

One of the most commonly used metal materials for the manufacture of biomedical implants are stainless steel and titanium-based alloys. Due to the specific conditions and complex environment in the human body, different strategies have been employed to protect them and improve their functionality in vivo. In this thesis, a …

Surfaces and interfaces in the growth of SrTiO3 on Si by pulsed laser deposition

Author(s): Tjaša Parkelj Potočnik (Author), Matjaž Spreitzer (Supervisor)

Year: 2021

Type: Doctoral dissertation

SrTiO3 (STO) thin films are used as buffer layers that enable epitaxial integration of various functional oxides with silicon. When pulsed laser deposition (PLD) is used to grow STO on Si, a thin amorphous layer is formed at the STO-Si interface that limits the use of such heterostructures in certain …

Investigations and separation of various contributions to dielectric response of advanced ceramic and polymeric materials

Author(s): Andreja Eršte (Author), Vid Bobnar (Supervisor)

Year: 2013

Type: Doctoral dissertation

Dielectric materials, used to control and store charges and electric energy, play a key role in modern electronics and electric power systems. Dielectric spectroscopy is a versatile method, well-suited for detection, separation and characterization of various contributions to dielectric response of advanced ceramic and polymeric materials, as it enables understanding …

Synthesis and functionalisation of one-dimensional titanate-based nanostructures

Author(s): Ines Bračko (Author), Danilo Suvorov (Supervisor), Boštjan Jančar (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

One-dimensional hydrothermally synthesized nanostructures such as nanotubes and nanobelts composed of layered titanates from A2TinO2n+1 family have attracted great interest due to their high specific surface area, ion-exchange ability and semiconducting properties, which make them promising candidates for potential applications in the field of catalysis, gas sensors, dye-sensitized solar cells, …

Processing-Dependent Broadband Dielectric Properties of KTaO3 Ceramics, Films and KTa0.6Nb0.4O3 Films

Author(s): Sebastjan Glinšek (Author), Marija Kosec (Supervisor), Zdravko Kutnjak (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

KTaO3 belongs to the group of incipient ferroelectrics, which are materials important from the fundamental, as well as from the applications, point of view. It is well known in its single-crystal form; however, the processing of technologically interesting ceramics and thin films is a challenging task and knowledge of their …

Synthesis and Characterization of Bi12SiO20 Thin Films Prepared by Sol-gel Method

Author(s): Asja Veber (Author), Danilo Suvorov (Supervisor)

Year: 2010

Type: Doctoral dissertation

The sillenites Bi12MO20 (M = Si, Ge, Ti, Pb, Mn, B1/2P1/2) have been recognised as promising bulk materials for electronic applications because their dielectric properties (5.5 GHz: ε = 37.4 - 41, τf = -19 – (-84) ppm/K, Q x f = 800 - 8100 and Tsin = 680 - …