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Heterogeneous recombination of neutral oxygen atoms on the surfaces of oxidized materials

Author(s): Domen Paul (Author), Miran Mozetič (Supervisor), Rok Zaplotnik (Co-Supervisor)

Year: 2024

Type: Doctoral dissertation

In this dissertation, we studied heterogeneous surface recombination of neutral oxygen atoms. We described plasma as a reliable source of neutral oxygen atoms and the behavior of neutral atoms in low-pressure plasma sustained by high-frequency discharges. Neutral atom density in the flowing afterglow and the recombination coefficient on several surfaces …

Crystal structure and phase transformations in 1D nanostructures

Author(s): Martin Košiček (Author), Uroš Cvelbar (Supervisor), Janez Zavašnik (Co-Supervisor), Uroš Puc (Co-Supervisor)

Year: 2023

Type: Doctoral dissertation

Metal oxide and sulfide nanostructures are a versatile family of materials with wide-ranging applications, and their development remains ongoing. In nanoscience, attention is being directed towards their synthesis and further advancement, including the creating of new complex structures and morphologies. In this regard, ion-exchange reactions have emerged as a cutting-edge …

Interactions of azole molecules with copper ions and copper surfaces covered with chemisorbed H, O, Oh or Cl

Author(s): Matjaž Dlouhy (Author), Anton Kokalj (Supervisor)

Year: 2023

Type: Doctoral dissertation

In real environments, copper and other metal surfaces are never clean. Even during active dissolution in corrosion, they are likely to be covered with adsorbed corrosion-relevant species such as O, OH, H, and Cl. To explore the impact of such species on the bonding of imidazole, used herein as an …

Speciation of ruthenium-based candidate drugs for cancer treatment and copper as a potential biomarker for cancer diagnosis in human serum

Author(s): Katarina Marković (Author), Radmila Milačič (Supervisor)

Year: 2022

Type: Doctoral dissertation

According to the World Health Organization (WHO), cancer represents the second leading cause of mortality, with almost 10 million deaths in 2020. A broad spectra of cancer treatments are being developed, among them are metal-based drugs. Consistent with the available data, platinum (Pt)-based chemotherapeutics are still widely used to treat …

Synergistic action of organic inhibitors to mitigate corrosion of aluminium, copper and aluminium-copper alloy in chloride solution

Author(s): Dževad Kozlica (Author), Ingrid Milošev (Supervisor)

Year: 2022

Type: Doctoral dissertation

The inhibitory action of organic compounds, 2-mercaptobenzimidazole (MBI), octylphosphonic acid (OPA) and their binary combinations was studied on aluminium, copper and aluminium alloy (AA) 2024 in chloride environments by ex-situ conventional electrochemical methods and surface-analytical techniques. In addition, the influence of pre-treatment of the metal surface and the choice of …

Contribution to understanding of the mechanism of amyloid fibril formation and its effects on the cell

Author(s): Katja Škerget (Author), Eva Žerovnik; (Supervisor), Uroš Petrovič (Co-Supervisor)

Year: 2011

Type: Doctoral dissertation

The presence of insoluble amyloid aggregates in various human tissues correlates with the development of many human disorders (amyloidoses), including neurodegenerative diseases. Deposition of the aggregated misfolded proteins in the brain, where aggregates can be localized extracellularly or intracellularly, is the main characteristic of Alzheimer's, Parkinson's, Huntington's, prion diseases and …

Hydraulic load cells for measurement of small loads

Author(s): Roman Pačnik (Author), Franc Novak (Supervisor), Marija Kosec (Co-Supervisor)

Year: 2011

Type: Doctoral dissertation

This work deals with the design of a small kitchen appliance with a weighing function integrated into a control loop in order to prevent unbalanced movement of the appliance during operation. In this particular case, the weighing should be appropriate for larger amounts (up to 5 kg) of ingredients. The …

Low-temperature STM study and manipulation of single atoms and nanostructures

Author(s): Erik Zupanič (Author), Albert Prodan (Supervisor), Miha Škarabot (Co-Supervisor)

Year: 2010

Type: Doctoral dissertation

The theory behind scanning tunneling microscopy and spectroscopy is presented and the basic manipulation techniques are described. Construction details of a low-temperature scanning tunneling microscope for single atom manipulation experiments are given. Single crystal copper (111) and (211) surfaces are studied. Single atom extraction, followed by lateral manipulation procedures is …

Hydrogen absorption in Ti-Zr-Ni alloys

Author(s): Andraž Kocjan (Author), Spomenka Kobe (Supervisor), Paul McGuiness (Co-Supervisor)

Year: 2009

Type: Doctoral dissertation

Our research focused on the formation of Ti40Zr40-xNi20Cux (x=3, 5), Ti45Zr38-xNi17Cux (x=3, 5), Ti53Zr27-xNi20Cux (x=3, 5) and Ti58Zr24-xNi18Cux (x=3, 5) icosahedral (i-phase) quasicrystals by three different techniques and their subsequent characterization and high-pressure hydrogenation. The quasicrystals of this system are thermodynamically stable and they have a relatively good affinity for …