Dielectric materials are essential components of electronic devices and electric power systems. Consequently, the design and development of new materials with enhanced dielectric response remain of great importance. This dissertation examines three different approaches to enhancing the dielectric response: (i) percolative composites, (ii) polymer blending, and (iii) the induction of …
Synthesized in green plants, cellulose is the most abundant natural biopolymer on the planet and is thus widely available, cheap and renewable. Furthermore, its hierarchical structure allows extraction of nanosized particles in the form of cellulose nanocrystals (CNCs), obtained with hydrolysis or cellulose nanofibrils (CNFs), isolated through chemical, biological pretreatment …
Alkali activation is a chemical process in which aluminosilicate-rich materials that dissolve in basic media at room temperature form binding phases by polycondensation. Alkali-activated materials (AAM), also called geopolymers, are inorganic aluminosilicate-based materials produced mainly from fly ashes and metallurgical slags or clays with high Al and Si content and …
This thesis focuses on the fate of chosen antidepressants in the environment. Studied compounds belong to the class of selective serotonin reuptake inhibitors. Reportedly they do not completely mineralize by existing water treatment processes and their residues cause unwanted toxic effects in aquatic organisms. However, to date, insufficient information has …
The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …
An everyday awareness of the presence of harmful chemicals around us has led to the development of a way to report overexposure through the reactions of these compounds with specifically prepared materials - sensory elements. In this doctoral dissertation we focused on the electrochemical synthesis (electropolymerization) of conductive polymer polyaniline …
The inhibitory action of organic compounds, 2-mercaptobenzimidazole (MBI), octylphosphonic acid (OPA) and their binary combinations was studied on aluminium, copper and aluminium alloy (AA) 2024 in chloride environments by ex-situ conventional electrochemical methods and surface-analytical techniques. In addition, the influence of pre-treatment of the metal surface and the choice of …
The scientific backgrounds of technologies involved in the production of headlamps for the automotive industry are elaborated in this thesis. The experimental work was performed using an industrial plasma reactor with a volume of approximately 5 m3. The reactor enables three different operations, i.e., plasma pretreatment of workpieces made from …
Vascular grafts made of polyethyleneterephthalate (PET) polymers have successfully replaced large-diameter blood vessels, but the long-term performance of small-diameter (< 6 mm) vascular grafts is still disappointing. The main problem is insufficient biocompatibility of polymer surface with blood, which causes complications after implementation; such as thrombosis or restenosis. These complications …