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Cold sintering of lead-free ferroelectric perovskites

Author(s): Samir Salmanov (Author), Mojca Otoničar (Supervisor), Danjela Kuščer Hrovatin (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Fabrication of electroceramics usually requires high sintering temperatures of 800 to 1400 °C, which can unintentionally lead to problems such as volatilization of species, formation of secondary phases and excessive grain growth. These problems can cause inhomogeneous microstructures, non-stoichiometric chemical compositions and limited material functionality. Therefore, there is a need …

Microstructure development in lithium lanthanum titanate solid electrolyte

Author(s): Petruša Borštnar (Author), Nina Daneu (Supervisor)

Year: 2025

Type: Doctoral dissertation

All-solid-state batteries are one of the key technologies for future energy storage and the transition to a climate-neutral society. They offer improved safety, stability, and a broader operating temperature range compared to conventional batteries with liquid electrolyte. Perovskite Li0.33La0.56 0.11TiO3 (LLTO) is recognized as one of the most promising solid …

Microstructural analysis and evaluation OF W and W/W2C composites for fusion application

Author(s): Andreja Šestan (Author), Miran Čeh (Supervisor), Saša Novak Krmpotič (Co-Supervisor)

Year: 2023

Type: Doctoral dissertation

Fusion technology has a great potential to safely provide an inexhaustible quantity of electricity without producing greenhouse gases and minimal hazardous waste compared to conventional energy sources, such as nuclear power plants. For materials intended for fusion plasma-facing applications, the essential properties are structural stability at elevated temperature, adequate thermal …

Lead magnesium niobate titanate thick films prepared by aerosol deposition method

Author(s): Matej Šadl (Author), Hana Uršič Nemevšek (Supervisor)

Year: 2022

Type: Doctoral dissertation

The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …

Processing of heavy-rare-earth-lean Nd-Fe-B permanent magnets for high-temptrature applications

Author(s): Matic Korent (Author), Kristina Žagar Soderžnik (Supervisor), Spomenka Kobe (Co-Supervisor)

Year: 2021

Type: Doctoral dissertation

Permanent magnets are materials that generate a magnetic field in free space without electricity or other external energy sources. They are essential components of modern technologies, used in many electrical devices. Nowadays, they are included in technology for renewable sources of energy, such as electrical vehicles, generators and wind turbines. …

Sintering and phase transition behaviour of sodium niobate

Author(s): Jurij Koruza (Author), Barbara Malič (Supervisor), Tadej Rojac (Co-Supervisor)

Year: 2013

Type: Doctoral dissertation

Sodium niobate (NaNbO3) is the end member of several alkaline niobate-based solid solutions, which represent an important group of environment-friendly lead-free piezoceramics. Even though alkaline niobates are of considerable technological importance, problems in obtaining high densities and a fine-grained microstructure are still reported and not much is known about the …

Development of coatings on Ti6Al4V alloy for new generation bone implants with improved osseointegration

Author(s): Nataša Drnovšek (Author), Saša Novak Krmpotič (Supervisor)

Year: 2012

Type: Doctoral dissertation

The aging of bone tissue, bone defects that form during the removal of cysts, tumours, genetic defects and other bone‐tissue‐related diseases, together with demands for a better quality of life, mean a requirement for materials, artificial or autogenous, that will have a long functionality and survivability under the body’s environmental …

Low-temperature sintering of piezoelectric K0.5Na0.5NbO3 ceramics

Author(s): Janez Bernard (Author), Barbara Malič (Supervisor), Andreja Benčan Golob (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

The KNN solid solution was prepared from pre-synthesized binary compounds of, sodium and potassium niobate in a 1/1 molar ratio. The KNG sintering aid was prepared by homogenizing the pre-reacted binary mixtures of alkaline reagents and germanium oxide with the Na/Ge = 1/1 and K/Ge = 1/1 molar ratios. The …

Controlled synthesis of TiO2 nanoparticles and their application in photovoltaics

Author(s): Dejan Verhovšek (Author), Miran Čeh (Supervisor)

Year: 2012

Type: Doctoral dissertation

Titanium dioxide (TiO2) in nanoparticle form has recently gained a lot of attention, in both the scientific and industrial communities. This is due to the fact that it exhibits various interesting chemical and physical characteristics, for example, a high photocatalytic activity and the absorption of incident UV light. Many applications …

Moderately porous zirconia ceramics for dental applications

Author(s): Sebastjan Perko (Author), Tomaž Kosmač (Supervisor), Aleš Dakskobler (Co-Supervisor)

Year: 2012

Type: Doctoral dissertation

This doctoral thesis describes the preparation of moderately porous Y-TZP ceramics with improved flexural strength. The main field of application is dentistry, where the elastic mismatch between the Y-TZP material and tooth substance influences the survival rate of fixed partial dentures (FPDs). By introducing porosity into the bulk samples a …