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Dielectric materials are essential components of electronic devices and electric power systems. Consequently, the design and development of new materials with enhanced dielectric response remain of great importance. This dissertation examines three different approaches to enhancing the dielectric response: (i) percolative composites, (ii) polymer blending, and (iii) the induction of …

Fabrication of electroceramics usually requires high sintering temperatures of 800 to 1400 °C, which can unintentionally lead to problems such as volatilization of species, formation of secondary phases and excessive grain growth. These problems can cause inhomogeneous microstructures, non-stoichiometric chemical compositions and limited material functionality. Therefore, there is a need …

Barium zirconate titanate-barium calcium titanate 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) ceramic exhibits a high piezoelectric response in the vicinity of room temperature. It is an environment-friendly alternative to Pb(Zr1-xTix)O3 (PZT), the most used ceramic material in piezoelectric applications. Thin films meet the requirements related to the miniaturization of electronic components such as in …

All-solid-state batteries are one of the key technologies for future energy storage and the transition to a climate-neutral society. They offer improved safety, stability, and a broader operating temperature range compared to conventional batteries with liquid electrolyte. Perovskite Li0.33La0.56 0.11TiO3 (LLTO) is recognized as one of the most promising solid …

In the scope of this thesis, I focused on SrTiO3 (ST)-based dielectric ceramic composites as a lead-free perovskite material, which holds great potential for use in various electronic components. Such materials are large-scale and fabricated under high energy requirements, indicating an increasing need for a more environmentally friendly processing method. …

The first part of the thesis deals with the impact of surface-functionalized nanoparticles (NP) can have on the stability of liquid crystal (LC) phases. Experimental data of NP concentration-driven phase transition between the isotropic and nematic phase in 5OO8 LCs were used to create a minimal mathematical model that would …

The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …

We are speeding full throttle towards a climate catastrophe and we have only until 2030 to take action to avoid the most devastating and unimaginable consequences. The lack of political and corporate will to change the status quo of “business as usual” is causing mass protests and civil disobedience globally. …

Highly porous ceramic γ‒Al2O3 monoliths are important in many applications, e.g., catalysis, thermal insulation and adsorption, yet they still have a lot of unrecognized potential. There is a lot of incentive to employ simple and green fabrication processes for the preparation of such porous ceramic materials; however, many challenges, especially …

Tin (IV) oxide, SnO2 (cassiterite), is an n-type semiconductor with an advantageous combination of chemical, electric and optical properties that make it suitable for a range of applications, from solid-state gas sensors, transparent conductive coatings, oxidation catalysts and varistors. In varistor ceramics, grain growth studies are of particular interest, because …