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Microstructure design and multifunctionality of barium zirconate titanate-barium calcium titanate thin films prepared by chemical solution deposition

Author(s): Sabi William Konsago (Author), Barbara Malič (Supervisor), Hana Uršič Nemevšek (Co-Supervisor)

Year: 2025

Type: Doctoral dissertation

Barium zirconate titanate-barium calcium titanate 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BZT-BCT) ceramic exhibits a high piezoelectric response in the vicinity of room temperature. It is an environment-friendly alternative to Pb(Zr1-xTix)O3 (PZT), the most used ceramic material in piezoelectric applications. Thin films meet the requirements related to the miniaturization of electronic components such as in …

Lead magnesium niobate titanate thick films prepared by aerosol deposition method

Author(s): Matej Šadl (Author), Hana Uršič Nemevšek (Supervisor)

Year: 2022

Type: Doctoral dissertation

The miniaturization of electronic devices requires the fabrication of functional components in the form of μm-sized thick films. Some of the most promising functional materials are relaxor-ferroelectric (1-x)Pb(Mg1/3Nb2/3)O3–xPbTiO3 (PMN–100xPT), as they exhibit versatile dielectric, piezoelectric and relaxor-ferroelectric properties. However, the integration of functional ceramic thick films with non-conventional substrates such …

Protection of biomedical alloys by thin films of alumina and hafnia prepared by atomic layer deposition

Author(s): Ivan Spajić (Author), Ingrid Milošev (Supervisor)

Year: 2022

Type: Doctoral dissertation

One of the most commonly used metal materials for the manufacture of biomedical implants are stainless steel and titanium-based alloys. Due to the specific conditions and complex environment in the human body, different strategies have been employed to protect them and improve their functionality in vivo. In this thesis, a …

Structural and electrical properties of 0.65PMN-0.35PT thick films on different substrates

Author(s): Hana Uršič Nemevšek (Author), Marija Kosec (Supervisor), Marko Hrovat (Co-Supervisor)

Year: 2010

Type: Doctoral dissertation

A starting powder with the nominal composition 0.65Pb(Mg1/3Nb2/3)O3–0.35PbTiO3 (0.65PMN–0.35PT), which corresponds to the morphotropic phase boundary (MPB) composition, was prepared by mechanochemical activation followed by attritor milling and low-temperature calcination at 700°C. It had a narrow particle size distribution with the median particle size equal to 0.3 μm. From the …